Reaction of Arenes with Iodine in the Presence of Potassium Peroxodisulfate in Trifluoroacetic Acid. Direct and Simple Synthesis of Diaryliodonium Triflates

Reaction of Arenes with Iodine in the Presence of Potassium Peroxodisulfate in Trifluoroacetic Acid. Direct and Simple Synthesis of Diaryliodonium Triflates

Diaryliodonium triflates have been directly prepared by reaction of arenes with elemental iodine in good yields by using K2S2O8 and TFA, followed by treatment with NaOTf. This procedure avoids the use of high temperature and severe reaction conditions.

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Veröffentlicht in:Journal of organic chemistry 2006-12, Vol.71 (26), p.9903-9905
Hauptverfasser: Hossain, Md. Delwar, Ikegami, Yasuyuki, Kitamura, Tsugio
Format: Artikel
Sprache:eng
Schlagworte:
Benzene Derivatives - chemistry
Chemistry
Exact sciences and technology
Hydrocarbons, Iodinated - chemical synthesis
Hydrocarbons, Iodinated - chemistry
Iodine - chemistry
Organic chemistry
Potassium Compounds - chemistry
Sulfates - chemistry
Trifluoroacetic Acid - chemistry
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Zusammenfassung:Diaryliodonium triflates have been directly prepared by reaction of arenes with elemental iodine in good yields by using K2S2O8 and TFA, followed by treatment with NaOTf. This procedure avoids the use of high temperature and severe reaction conditions.
ISSN:0022-3263
1520-6904
DOI:10.1021/jo061889q