Synthesis of Pentafluorosulfanyl Trifluorovinyl Ether and Its Facile Rearrangement to Difluoro(pentafluorosulfanyl)acetyl Fluoride

Synthesis of Pentafluorosulfanyl Trifluorovinyl Ether and Its Facile Rearrangement to Difluoro(pentafluorosulfanyl)acetyl Fluoride

A radical departure: A novel fluorinated vinyl ether 1 was synthesized and was found to undergo an unexpected facile rearrangement to give compound 2, which was confirmed to be a radical process by EPR spectroscopy.

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Veröffentlicht in:Angewandte Chemie (International ed.) 2007-01, Vol.46 (35), p.6626-6628
Hauptverfasser: Du, Libin, Elliott, Bevan, Echegoyen, Luis, DesMarteau, Darryl D
Format: Artikel
Sprache:eng
Schlagworte:
EPR spectroscopy
fluorine
NMR spectroscopy
radical reactions
rearrangement
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Beschreibung
Zusammenfassung:A radical departure: A novel fluorinated vinyl ether 1 was synthesized and was found to undergo an unexpected facile rearrangement to give compound 2, which was confirmed to be a radical process by EPR spectroscopy.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.200702425