Metal-Complex-Decorated Homochiral Heterobimetallic Telluride Single-Stranded Helix

Metal-Complex-Decorated Homochiral Heterobimetallic Telluride Single-Stranded Helix

Solvothermal reaction of a mixture of Sn, Mn, and Te at 200 °C using teta as the solvent yields a novel inorganic−organic hybrid solid [Mn(teta)(en)]·[Mn(teta)][Mn(SnTe4)2·Mn(teta)] (teta = triethylenetetramine and en = ethylenediamine; 1), which has a homochiral single-stranded helical structure. T...

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Veröffentlicht in:Inorganic chemistry 2007-09, Vol.46 (18), p.7262-7264
Hauptverfasser: Zhang, Qichun, Bu, Xianhui, Lin, Zhien, Biasini, Maurizio, Beyermann, W. P, Feng, Pingyun
Format: Artikel
Sprache:eng
Schlagworte:
Metals - chemistry
Models, Molecular
Molecular Conformation
Spectrophotometry
Stereoisomerism
Tellurium - chemistry
Temperature
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Beschreibung
Zusammenfassung:Solvothermal reaction of a mixture of Sn, Mn, and Te at 200 °C using teta as the solvent yields a novel inorganic−organic hybrid solid [Mn(teta)(en)]·[Mn(teta)][Mn(SnTe4)2·Mn(teta)] (teta = triethylenetetramine and en = ethylenediamine; 1), which has a homochiral single-stranded helical structure. The material is a semiconductor with a band gap of 0.88 eV and shows paramagnetic behavior between 2 and 300 K.
ISSN:0020-1669
1520-510X
DOI:10.1021/ic701135h