Long-Lived and Efficient Emission from Mononuclear Amidophosphine Complexes of Copper

Long-Lived and Efficient Emission from Mononuclear Amidophosphine Complexes of Copper

A number of structurally unusual, monomeric amidophosphine complexes of copper exhibit luminescence properties that are unprecedented for monocopper systems in solution at room temperature. The complexes exhibit lifetimes as long as 150 μs in benzene and quantum efficiencies in the range of 0.16 <...

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Veröffentlicht in:Inorganic chemistry 2007-09, Vol.46 (18), p.7244-7246
Hauptverfasser: Miller, Alexander J. M, Dempsey, Jillian L, Peters, Jonas C
Format: Artikel
Sprache:eng
Schlagworte:
Copper - chemistry
Models, Molecular
Molecular Structure
Organometallic Compounds - chemistry
Phosphines - chemistry
Photochemistry
Time Factors
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Zusammenfassung:A number of structurally unusual, monomeric amidophosphine complexes of copper exhibit luminescence properties that are unprecedented for monocopper systems in solution at room temperature. The complexes exhibit lifetimes as long as 150 μs in benzene and quantum efficiencies in the range of 0.16 < φ < 0.70.
ISSN:0020-1669
1520-510X
DOI:10.1021/ic7009513