Parallel Syntheses of (+)- and (-)-α-Cuparenone by Radical Combination in Crystalline Solids

Parallel Syntheses of (+)- and (-)-α-Cuparenone by Radical Combination in Crystalline Solids

Photo[Organic]synthesis: Irradiation of well‐designed crystalline ketones can result in the solvent‐free generation of compounds having adjacent quaternary stereogenic centers, as illustrated for the enantiospecific synthesis of the natural products (+)‐ and (−)‐(α)‐cuparenone (see picture)....

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Veröffentlicht in:Angewandte Chemie (International ed.) 2007-01, Vol.46 (34), p.6485-6487
Hauptverfasser: Natarajan, Arunkumar, Ng, Danny, Yang, Zhe, Garcia-Garibay, Miguel A
Format: Artikel
Sprache:eng
Schlagworte:
enantioselectivity
photodecarbonylation
solid-state reactions
solid-state structures
sustainable chemistry
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Zusammenfassung:Photo[Organic]synthesis: Irradiation of well‐designed crystalline ketones can result in the solvent‐free generation of compounds having adjacent quaternary stereogenic centers, as illustrated for the enantiospecific synthesis of the natural products (+)‐ and (−)‐(α)‐cuparenone (see picture).
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.200700679