The dramatic acceleration effect of imidazolium ionic liquids on electron transfer reactions

The dramatic acceleration effect of imidazolium ionic liquids on electron transfer reactions

Imidazolium ionic liquids (ILs) exhibited a dramatic acceleration effect on the electron transfer from metal complexes such as (C(5)Me(5))(2)Fe(II) and (C(5)Me(5))(2)Co(II) to the oxygen molecule; this acceleration effect can be ascribed to the stabilization of the oxygen radical anions by coordinat...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2007-01 (33), p.3467-3469
Hauptverfasser: Choi, Doo Seong, Kim, Dong Hyun, Shin, Ueon Sang, Deshmukh, Ravindra R, Lee, Sang-gi, Song, Choong Eui
Format: Artikel
Sprache:eng
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Zusammenfassung:Imidazolium ionic liquids (ILs) exhibited a dramatic acceleration effect on the electron transfer from metal complexes such as (C(5)Me(5))(2)Fe(II) and (C(5)Me(5))(2)Co(II) to the oxygen molecule; this acceleration effect can be ascribed to the stabilization of the oxygen radical anions by coordinating with the acidic C2-H of imidazolium ILs.
ISSN:1359-7345
1364-548X
DOI:10.1039/b708044a