A high-performance selective oxidation system for the facile production of fine chemicals

A high-performance selective oxidation system for the facile production of fine chemicals

Mn(III)AlPO-5 and Cr(VI)AlPO-5 redox (microporous) catalysts are effective, in the presence of dissolved acetylperoxyborate (APB) under mild conditions (333-373 K), and much superior to the titanosilicate, TS-1 (also a single-site heterogeneous catalyst), in the selective oxidation of primary, secon...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2007-01 (19), p.1924-1926
Hauptverfasser: Raja, Robert, Thomas, John Meurig, Greenhill-Hooper, Mike, Doukova, Violeta
Format: Artikel
Sprache:eng
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Zusammenfassung:Mn(III)AlPO-5 and Cr(VI)AlPO-5 redox (microporous) catalysts are effective, in the presence of dissolved acetylperoxyborate (APB) under mild conditions (333-373 K), and much superior to the titanosilicate, TS-1 (also a single-site heterogeneous catalyst), in the selective oxidation of primary, secondary, benzylic and other unsaturated alcohols, p-cymene, methyl cyclohexene and other speciality organics which are of value in the fine-chemical and pharmaceutical industries.
ISSN:1359-7345
1364-548X
DOI:10.1039/b618090f