Polyazidopyrimidines: High-Energy Compounds and Precursors to Carbon Nanotubes

Polyazidopyrimidines: High-Energy Compounds and Precursors to Carbon Nanotubes

An additional azidomethyl group dramatically decreases the melting points of the corresponding azidopyrimidines. Theoretical calculations show that these polyazido compounds (see picture; N light blue, C dark blue, H white) exhibit highly promising energetic properties. 2,4,6‐Triazidopyrimidine was...

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Veröffentlicht in:Angewandte Chemie International Edition 2006-11, Vol.45 (43), p.7262-7265
Hauptverfasser: Ye, Chengfeng, Gao, Haixiang, Boatz, Jerry A., Drake, Gregory W., Twamley, Brendan, Shreeve, Jean'ne M.
Format: Artikel
Sprache:eng
Schlagworte:
azides
Azides - chemical synthesis
Azides - chemistry
Crystallography, X-Ray
explosives
heats of formation
Ligands
Models, Molecular
Molecular Structure
nanotubes
Nanotubes, Carbon - chemistry
nitrogen
Particle Size
Polymers - chemical synthesis
Polymers - chemistry
Pyrimidines - chemical synthesis
Pyrimidines - chemistry
Quantum Theory
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Zusammenfassung:An additional azidomethyl group dramatically decreases the melting points of the corresponding azidopyrimidines. Theoretical calculations show that these polyazido compounds (see picture; N light blue, C dark blue, H white) exhibit highly promising energetic properties. 2,4,6‐Triazidopyrimidine was found to be a novel precursor to carbon nanotubes in the presence of Ni(ClO4)2.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.200602778