An unprecedented heterotrimetallic Fe/Cu/Co core for mild and highly efficient catalytic oxidation of cycloalkanes by hydrogen peroxide

An unprecedented hexanuclear heterotrimetallic Fe/Cu/Co complex bearing two Cu(mu-O)2Co(mu-O)2Fe cores is easily prepared by self-assembly and acts as a remarkable catalyst for the peroxidative oxidation of cycloalkanes under mild conditions.

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2006-01 (44), p.4605-4607
Hauptverfasser: Nesterov, Dmytro S, Kokozay, Volodymyr N, Dyakonenko, Viktoriya V, Shishkin, Oleg V, Jezierska, Julia, Ozarowski, Andrew, Kirillov, Alexander M, Kopylovich, Maximilian N, Pombeiro, Armando J L
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Sprache:eng
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Zusammenfassung:An unprecedented hexanuclear heterotrimetallic Fe/Cu/Co complex bearing two Cu(mu-O)2Co(mu-O)2Fe cores is easily prepared by self-assembly and acts as a remarkable catalyst for the peroxidative oxidation of cycloalkanes under mild conditions.
ISSN:1359-7345
1364-548X
DOI:10.1039/b608790f