A spectroscopic characterization of the electronic ground state of rhodium monoboride
A laser-induced fluorescence electronic spectrum of RhB is reported. It is the first such known example for a metal monoboride. Rh B 10 and Rh B 11 species are observed in natural abundance. The molecular ground state has Σ + 1 symmetry, an r 0 bond length of 0.169 nm , and a vibrational frequency o...
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| Veröffentlicht in: | The Journal of chemical physics 2006-06, Vol.124 (21), p.216101-216101-2 |
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| Hauptverfasser: | , |
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| Sprache: | eng |
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| container_end_page | 216101-2 |
|---|---|
| container_issue | 21 |
| container_start_page | 216101 |
| container_title | The Journal of chemical physics |
| container_volume | 124 |
| creator | Chowdhury, Pradyot K. Balfour, Walter J. |
| description | A laser-induced fluorescence electronic spectrum of RhB is reported. It is the first such known example for a metal monoboride.
Rh
B
10
and
Rh
B
11
species are observed in natural abundance. The molecular ground state has
Σ
+
1
symmetry, an
r
0
bond length of
0.169
nm
, and a vibrational frequency of
∼
920
cm
−
1
. |
| doi_str_mv | 10.1063/1.2207615 |
| format | Article |
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Rh
B
10
and
Rh
B
11
species are observed in natural abundance. The molecular ground state has
Σ
+
1
symmetry, an
r
0
bond length of
0.169
nm
, and a vibrational frequency of
∼
920
cm
−
1
.</description><identifier>ISSN: 0021-9606</identifier><identifier>EISSN: 1089-7690</identifier><identifier>DOI: 10.1063/1.2207615</identifier><identifier>PMID: 16774442</identifier><identifier>CODEN: JCPSA6</identifier><language>eng</language><publisher>United States: American Institute of Physics</publisher><ispartof>The Journal of chemical physics, 2006-06, Vol.124 (21), p.216101-216101-2</ispartof><rights>2006 American Institute of Physics</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c338t-9c05ead315135040ca4d13b0b900c1a595beb94914b1ccf06fd129329dcd354b3</citedby><cites>FETCH-LOGICAL-c338t-9c05ead315135040ca4d13b0b900c1a595beb94914b1ccf06fd129329dcd354b3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,790,1553,4498,27901,27902</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/16774442$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Chowdhury, Pradyot K.</creatorcontrib><creatorcontrib>Balfour, Walter J.</creatorcontrib><title>A spectroscopic characterization of the electronic ground state of rhodium monoboride</title><title>The Journal of chemical physics</title><addtitle>J Chem Phys</addtitle><description>A laser-induced fluorescence electronic spectrum of RhB is reported. It is the first such known example for a metal monoboride.
Rh
B
10
and
Rh
B
11
species are observed in natural abundance. The molecular ground state has
Σ
+
1
symmetry, an
r
0
bond length of
0.169
nm
, and a vibrational frequency of
∼
920
cm
−
1
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Rh
B
10
and
Rh
B
11
species are observed in natural abundance. The molecular ground state has
Σ
+
1
symmetry, an
r
0
bond length of
0.169
nm
, and a vibrational frequency of
∼
920
cm
−
1
.</abstract><cop>United States</cop><pub>American Institute of Physics</pub><pmid>16774442</pmid><doi>10.1063/1.2207615</doi><tpages>1</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0021-9606 |
| ispartof | The Journal of chemical physics, 2006-06, Vol.124 (21), p.216101-216101-2 |
| issn | 0021-9606 1089-7690 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_68080165 |
| source | AIP Journals Complete; AIP Digital Archive |
| title | A spectroscopic characterization of the electronic ground state of rhodium monoboride |
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