A spectroscopic characterization of the electronic ground state of rhodium monoboride
A laser-induced fluorescence electronic spectrum of RhB is reported. It is the first such known example for a metal monoboride. Rh B 10 and Rh B 11 species are observed in natural abundance. The molecular ground state has Σ + 1 symmetry, an r 0 bond length of 0.169 nm , and a vibrational frequency o...
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Veröffentlicht in: | The Journal of chemical physics 2006-06, Vol.124 (21), p.216101-216101-2 |
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Hauptverfasser: | , |
Format: | Artikel |
Sprache: | eng |
Online-Zugang: | Volltext |
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Zusammenfassung: | A laser-induced fluorescence electronic spectrum of RhB is reported. It is the first such known example for a metal monoboride.
Rh
B
10
and
Rh
B
11
species are observed in natural abundance. The molecular ground state has
Σ
+
1
symmetry, an
r
0
bond length of
0.169
nm
, and a vibrational frequency of
∼
920
cm
−
1
. |
---|---|
ISSN: | 0021-9606 1089-7690 |
DOI: | 10.1063/1.2207615 |