A spectroscopic characterization of the electronic ground state of rhodium monoboride

A laser-induced fluorescence electronic spectrum of RhB is reported. It is the first such known example for a metal monoboride. Rh B 10 and Rh B 11 species are observed in natural abundance. The molecular ground state has Σ + 1 symmetry, an r 0 bond length of 0.169 nm , and a vibrational frequency o...

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Veröffentlicht in:The Journal of chemical physics 2006-06, Vol.124 (21), p.216101-216101-2
Hauptverfasser: Chowdhury, Pradyot K., Balfour, Walter J.
Format: Artikel
Sprache:eng
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Zusammenfassung:A laser-induced fluorescence electronic spectrum of RhB is reported. It is the first such known example for a metal monoboride. Rh B 10 and Rh B 11 species are observed in natural abundance. The molecular ground state has Σ + 1 symmetry, an r 0 bond length of 0.169 nm , and a vibrational frequency of ∼ 920 cm − 1 .
ISSN:0021-9606
1089-7690
DOI:10.1063/1.2207615