Cytochromes c‘:  Biological Models for the S = 3/2,5/2 Spin-State Admixture?

Cytochromes c‘:  Biological Models for the S = 3/2,5/2 Spin-State Admixture?

The electronic ground state of most known ferric heme proteins is either low-spin (S=1/2) or high-spin (S=5/2). However, a small group of proteins known as cytochromes c' have shown unusual electromagnetic properties. This review describes and discusses the results of studies on these proteins.

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Veröffentlicht in:Chemical reviews 2006-06, Vol.106 (6), p.2550-2579
Hauptverfasser: Weiss, Raymond, Gold, Avram, Terner, James
Format: Artikel
Sprache:eng
Schlagworte:
Animals
Biochemistry
Cytochromes c' - chemistry
Cytochromes c' - metabolism
Humans
Magnetism
Models, Chemical
Models, Molecular
Molecular Structure
Physics
Proteins
Proteins - chemistry
Quantum theory
Spectrum Analysis
Structure-Activity Relationship
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Zusammenfassung:The electronic ground state of most known ferric heme proteins is either low-spin (S=1/2) or high-spin (S=5/2). However, a small group of proteins known as cytochromes c' have shown unusual electromagnetic properties. This review describes and discusses the results of studies on these proteins.
ISSN:0009-2665
1520-6890
DOI:10.1021/cr040416l