A New Synthetic Approach to Phenol Derivatives: Use of Ring-Closing Olefin Metathesis

Phenol derivatives, which are one of the most important classes of aromatic compounds in organic chemistry, were synthesized by ruthenium-catalyzed ring-closing olefin metathesis (RCM) of 1,4,7-trien-3-ones with versatile substitution patterns. The RCM reaction for producing phenol derivatives was a...

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Veröffentlicht in:	Journal of the American Chemical Society 2005-08, Vol.127 (30), p.10470-10471
Hauptverfasser:	Yoshida, Kazuhiro, Imamoto, Tsuneo
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemistry Exact sciences and technology Noncondensed benzenic compounds Organic chemistry Preparations and properties
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container_title	Journal of the American Chemical Society
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creator	Yoshida, Kazuhiro Imamoto, Tsuneo
description	Phenol derivatives, which are one of the most important classes of aromatic compounds in organic chemistry, were synthesized by ruthenium-catalyzed ring-closing olefin metathesis (RCM) of 1,4,7-trien-3-ones with versatile substitution patterns. The RCM reaction for producing phenol derivatives was also successful with 1,5,7-trien-3-one as another precursor. Most of the phenols prepared here could not be obtained easily by conventional methods.
doi_str_mv	10.1021/ja050853x
format	Article
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title	A New Synthetic Approach to Phenol Derivatives: Use of Ring-Closing Olefin Metathesis
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