Novel spin transition between S = 5/2 and S = 3/2 in highly saddled iron(III) porphyrin complexes at extremely low temperatures

Novel spin transition between S = 5/2 and S = 3/2 in highly saddled iron(III) porphyrin complexes at extremely low temperatures

A novel spin transition between S = 5/2 and S = 3/2 has been observed for the first time in five-coordinate, highly saddled iron(III) porphyrinates by EPR and SQUID measurements at extremely low temperatures.

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Bibliographische Detailangaben
Veröffentlicht in:Chemical communications (Cambridge, England) England), 2006-05 (18), p.1935-1937
Hauptverfasser: Ohgo, Yoshiki, Chiba, Yuya, Hashizume, Daisuke, Uekusa, Hidehiro, Ozeki, Tomoji, Nakamura, Mikio
Format: Artikel
Sprache:eng
Schlagworte:
Cold Temperature
Electron Spin Resonance Spectroscopy
Hemin - chemistry
Magnetics
Models, Molecular
Molecular Structure
Sulfur - chemistry
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Zusammenfassung:A novel spin transition between S = 5/2 and S = 3/2 has been observed for the first time in five-coordinate, highly saddled iron(III) porphyrinates by EPR and SQUID measurements at extremely low temperatures.
ISSN:1359-7345
DOI:10.1039/b601412g