A concise synthesis of (-)-centrolobine via a diastereoselective ring rearrangement metathesis-isomerisation sequence

A total synthesis of (-)-centrolobine (1) based on a diastereoselective ring rearrangement metathesis-double bond isomerisation sequence and a one-pot cross metathesis-hydrogenation procedure is described.

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Veröffentlicht in:	Chemical communications (Cambridge, England) England), 2006-01 (18), p.1968-1970
Hauptverfasser:	Böhrsch, Verena, Blechert, Siegfried
Format:	Artikel
Sprache:	eng
Schlagworte:	Isomerism Molecular Structure Pyrans - chemical synthesis Pyrans - chemistry
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container_end_page	1970
container_issue	18
container_start_page	1968
container_title	Chemical communications (Cambridge, England)
container_volume
creator	Böhrsch, Verena Blechert, Siegfried
description	A total synthesis of (-)-centrolobine (1) based on a diastereoselective ring rearrangement metathesis-double bond isomerisation sequence and a one-pot cross metathesis-hydrogenation procedure is described.
doi_str_mv	10.1039/b602056a
format	Article
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source	MEDLINE; Royal Society of Chemistry Journals Archive (1841-2007); Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection
subjects	Isomerism Molecular Structure Pyrans - chemical synthesis Pyrans - chemistry
title	A concise synthesis of (-)-centrolobine via a diastereoselective ring rearrangement metathesis-isomerisation sequence
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