Liquid-phase oxidation of alkylaromatics by a H-atom transfer mechanism with a new heterogeneous CoSBA-15 catalyst

Liquid-phase oxidation of alkylaromatics by a H-atom transfer mechanism with a new heterogeneous CoSBA-15 catalyst

A new pseudo-tetrahedral Co(II) complex has been grafted onto the surface of SBA-15 and successfully utilized for the catalytic oxidization of alkylaromatic substrates with tert-butyl hydroperoxide (TBHP)via an H-atom transfer mechanism.

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Bibliographische Detailangaben
Veröffentlicht in:Chemical communications (Cambridge, England) England), 2005-08 (29), p.3736-3738
Hauptverfasser: Brutchey, Richard L, Drake, Ian J, Bell, Alexis T, Tilley, T Don
Format: Artikel
Sprache:eng
Schlagworte:
Alkylation
Catalysis
Hydrogen - chemistry
Molecular Structure
Organometallic Compounds - chemistry
Oxidation-Reduction
Silicon Dioxide
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Zusammenfassung:A new pseudo-tetrahedral Co(II) complex has been grafted onto the surface of SBA-15 and successfully utilized for the catalytic oxidization of alkylaromatic substrates with tert-butyl hydroperoxide (TBHP)via an H-atom transfer mechanism.
ISSN:1359-7345
1364-548X
DOI:10.1039/b506426k