One-Carbon Homologation of N-Sulfonylaziridines to Allylic Amines Using Dimethylsulfonium Methylide

One-Carbon Homologation of N-Sulfonylaziridines to Allylic Amines Using Dimethylsulfonium Methylide

Regio- and stereodefined allylic N-sulfonylamines are synthesized in high yields and under experimentally straightforward conditions by reaction of N-sulfonylaziridines with excess dimethylsulfonium methylide.

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Veröffentlicht in:Organic letters 2005-07, Vol.7 (15), p.3295-3298
Hauptverfasser: Hodgson, David M, Fleming, Matthew J, Stanway, Steven J
Format: Artikel
Sprache:eng
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Zusammenfassung:Regio- and stereodefined allylic N-sulfonylamines are synthesized in high yields and under experimentally straightforward conditions by reaction of N-sulfonylaziridines with excess dimethylsulfonium methylide.
ISSN:1523-7060
1523-7052
DOI:10.1021/ol051124p