Dynamic combinatorial olefin metathesis: templated synthesis of porphyrin boxes

A porphyrin macrocyclic square is efficiently prepared by a dynamic combinatorial approach to olefin metathesis and shown by scanning tunneling microscopy (STM) to self-assemble into highly ordered arrays on a graphite surface.

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2005-01 (28), p.3535-3537
Hauptverfasser: van Gerven, Paul C M, Elemans, Johannes A A W, Gerritsen, Jan W, Speller, Sylvia, Nolte, Roeland J M, Rowan, Alan E
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Sprache:eng
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Zusammenfassung:A porphyrin macrocyclic square is efficiently prepared by a dynamic combinatorial approach to olefin metathesis and shown by scanning tunneling microscopy (STM) to self-assemble into highly ordered arrays on a graphite surface.
ISSN:1359-7345
1364-548X
DOI:10.1039/b503619d