Ferrocenylalanes:  Solid-State and Solution Structures of Some New Aluminum-Bridged ansa-Ferrocenes

Ferrocenylalanes:  Solid-State and Solution Structures of Some New Aluminum-Bridged ansa-Ferrocenes

Addition of dilithiated ferrocene to AlEt2Cl and Al(κ2-C,NNMe2CH2C6H4)Cl2 yields the trimeric ferrocenyl derivative 1 and the dimeric [1,1‘]-ferrocenophane 2, respectively. Solution spectroscopy is consistent with the solid-state structures, which reveal unusual and unprecedented bonding around the...

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Veröffentlicht in:Inorganic chemistry 2005-07, Vol.44 (14), p.4906-4908
Hauptverfasser: Braunschweig, Holger, Burschka, Christian, Clentsmith, Guy K. B, Kupfer, Thomas, Radacki, Krzysztof
Format: Artikel
Sprache:eng
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Zusammenfassung:Addition of dilithiated ferrocene to AlEt2Cl and Al(κ2-C,NNMe2CH2C6H4)Cl2 yields the trimeric ferrocenyl derivative 1 and the dimeric [1,1‘]-ferrocenophane 2, respectively. Solution spectroscopy is consistent with the solid-state structures, which reveal unusual and unprecedented bonding around the aluminum centers.
ISSN:0020-1669
1520-510X
DOI:10.1021/ic0501925