New diphosphine ligands based on diphenyl ether for the Pd-catalyzed CO/ethene copolymerization

The catalytic activity and selectivity of palladium(II) complexes of new, flexible bidentate ligands in the CO/ethene copolymerization reaction have been found to change considerably with the steric properties of the ligands.

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Bibliographische Detailangaben
Veröffentlicht in:	Chemical communications (Cambridge, England) England), 2005-07 (27), p.3478-3480
Hauptverfasser:	Caporali, Maria, Müller, Christian, Staal, Bastiaan B P, Tooke, Duncan M, Spek, Anthony L, van Leeuwen, Piet W N M
Format:	Artikel
Sprache:	eng
Schlagworte:	Carbon Monoxide - chemistry Catalysis Ethylenes - chemistry Ligands Organometallic Compounds - chemistry Palladium - chemistry Phenyl Ethers - chemistry Phosphines - chemical synthesis Phosphines - chemistry Polymers - chemical synthesis Stereoisomerism
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Beschreibung
Zusammenfassung:	The catalytic activity and selectivity of palladium(II) complexes of new, flexible bidentate ligands in the CO/ethene copolymerization reaction have been found to change considerably with the steric properties of the ligands.
ISSN:	1359-7345 1364-548X
DOI:	10.1039/b503764f