Bis(2-butyl-N,N'-diisopropyl-amidinato)dichlorohafnium(IV)

Bis(2-butyl-N,N'-diisopropyl-amidinato)dichlorohafnium(IV)

The title compound, [Hf(C11H23N2)2Cl(2)], is a monomeric hafnium(IV) complex containing two bidentate amidinate ligands and two cis Cl atoms. The crystals are triclinic (space group P-1) and there is one independent six-coordinate monomer with a highly distorted octahedral geometry in the asymmetric...

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Veröffentlicht in:Acta crystallographica. Section C, Crystal structure communications Crystal structure communications, 2005-07, Vol.61 (Pt 7), p.m370-m372
Hauptverfasser: MILANOV, Andrian P, BHAKTA, Raghunandan, WINTER, Manuela, MERZ, Klaus, DEVI, Anjana
Format: Artikel
Sprache:eng
Schlagworte:
Condensed matter: structure, mechanical and thermal properties
Crystalline state (including molecular motions in solids)
Exact sciences and technology
Physics
Structure of solids and liquids
crystallography
Structure of specific crystalline solids
Theory of crystal structure, crystal symmetry
calculations and modeling
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Beschreibung
Zusammenfassung:The title compound, [Hf(C11H23N2)2Cl(2)], is a monomeric hafnium(IV) complex containing two bidentate amidinate ligands and two cis Cl atoms. The crystals are triclinic (space group P-1) and there is one independent six-coordinate monomer with a highly distorted octahedral geometry in the asymmetric unit. The reported structure is the first hafnium-amidinate complex to be characterized successfully by single-crystal X-ray diffraction.
ISSN:0108-2701
1600-5759
DOI:10.1107/S0108270105016872