Characterisation of the thermally accessible spin triplet state in dimers of the 7pi ClCNSSS+ in the solid state

Characterisation of the thermally accessible spin triplet state in dimers of the 7pi ClCNSSS+ in the solid state

[ClCNSSS]2(2+) is the first example of a thiazyl radical dimer where population of a thermally excited spin triplet state has been detected, as is proved by VT-powder and single-crystal EPR spectroscopy.

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2006-06 (21), p.2277-2279
Hauptverfasser: Cameron, T Stanley, Decken, Andreas, Kowalczyk, Radoslaw M, McInnes, Eric J L, Passmore, Jack, Rawson, Jeremy M, Shuvaev, Konstantin V, Thompson, Laurence K
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Sprache:eng
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Zusammenfassung:[ClCNSSS]2(2+) is the first example of a thiazyl radical dimer where population of a thermally excited spin triplet state has been detected, as is proved by VT-powder and single-crystal EPR spectroscopy.
ISSN:1359-7345