An achiral form of the hexameric resorcin[4]arene capsule sustained by hydrogen bonding with alcohols
The well-known hexameric capsules sustained by self-assembly of resorcin[4]arenes 1 with water molecules (1(6).(H2O)8) are shown to assemble similarly with (+/-)-2-ethylhexanol (2EH) as an achiral 1(6).(2EH)6.(H2O)2 species which further encapsulates 2EH.
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| Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2006-05 (20), p.2144-2146 |
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| Hauptverfasser: | , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | The well-known hexameric capsules sustained by self-assembly of resorcin[4]arenes 1 with water molecules (1(6).(H2O)8) are shown to assemble similarly with (+/-)-2-ethylhexanol (2EH) as an achiral 1(6).(2EH)6.(H2O)2 species which further encapsulates 2EH. |
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| ISSN: | 1359-7345 1364-548X |
| DOI: | 10.1039/b604148e |