Does coarsening begin during the initial stages of spinodal decomposition?
The initial stages of spinodal decomposition were studied by subjecting a critical blend of model polyolefins to a pressure quench and monitoring the evolution by time-resolved small angle neutron scattering. Contrary to the predictions of the widely accepted Cahn-Hilliard-Cook theory, we demonstrat...
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Veröffentlicht in: | The Journal of chemical physics 2005-06, Vol.122 (21), p.214903-214903 |
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Hauptverfasser: | , |
Format: | Artikel |
Sprache: | eng |
Online-Zugang: | Volltext |
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Zusammenfassung: | The initial stages of spinodal decomposition were studied by subjecting a critical blend of model polyolefins to a pressure quench and monitoring the evolution by time-resolved small angle neutron scattering. Contrary to the predictions of the widely accepted Cahn-Hilliard-Cook theory, we demonstrate that coarsening of the phase-separated structure begins immediately after the quench and occurs throughout the initial stages of spinodal decomposition. |
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ISSN: | 0021-9606 1089-7690 |
DOI: | 10.1063/1.1905584 |