Does coarsening begin during the initial stages of spinodal decomposition?

The initial stages of spinodal decomposition were studied by subjecting a critical blend of model polyolefins to a pressure quench and monitoring the evolution by time-resolved small angle neutron scattering. Contrary to the predictions of the widely accepted Cahn-Hilliard-Cook theory, we demonstrat...

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Veröffentlicht in:The Journal of chemical physics 2005-06, Vol.122 (21), p.214903-214903
Hauptverfasser: Rappl, Timothy J, Balsara, Nitash P
Format: Artikel
Sprache:eng
Online-Zugang:Volltext
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Zusammenfassung:The initial stages of spinodal decomposition were studied by subjecting a critical blend of model polyolefins to a pressure quench and monitoring the evolution by time-resolved small angle neutron scattering. Contrary to the predictions of the widely accepted Cahn-Hilliard-Cook theory, we demonstrate that coarsening of the phase-separated structure begins immediately after the quench and occurs throughout the initial stages of spinodal decomposition.
ISSN:0021-9606
1089-7690
DOI:10.1063/1.1905584