New routes to manganese higher-nuclearity topologies: synthesis of the cluster [Mn8(mu4-O)4(phpz)8(thf)4]

New routes to manganese higher-nuclearity topologies: synthesis of the cluster [Mn8(mu4-O)4(phpz)8(thf)4]

Reaction of Mn(ClO4)2.6H2O with 3(5)-methyl-5(3)-(2-hydroxyphenyl)pyrazole (H2phpz) affords a highly asymmetric octanuclear manganese(III) cluster resulting from the different bridging coordination modes of the ligand H2phpz.

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2005-07 (25), p.3147-3149
Hauptverfasser: Tanase, Stefania, Aromí, Guillem, Bouwman, Elisabeth, Kooijman, Huub, Spek, Anthony L, Reedijk, Jan
Format: Artikel
Sprache:eng
Schlagworte:
Crystallography, X-Ray
Manganese - chemistry
Models, Molecular
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Zusammenfassung:Reaction of Mn(ClO4)2.6H2O with 3(5)-methyl-5(3)-(2-hydroxyphenyl)pyrazole (H2phpz) affords a highly asymmetric octanuclear manganese(III) cluster resulting from the different bridging coordination modes of the ligand H2phpz.
ISSN:1359-7345
1364-548X
DOI:10.1039/b504215a