Interweaving of Triple-Helical and Extended Metal−O−Metal Single-Helical Chains with the Same Helix Axis in a 3D Metal−Organic Framework

A novel 3D metal−organic framework [Cd2(m-bptc)(4,4‘-bpy)0.5(H2O)4]·H2O (1; m-H4bptc = 1,1‘-biphenyl-2,3‘,3,4‘-tetracarboxylic acid, 4,4‘-bpy = 4,4‘-bipyridine) with interweaving of triple- and single-helical chains has been obtained based on hydro(solvo)thermal reactions.

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Bibliographische Detailangaben
Veröffentlicht in:	Inorganic chemistry 2006-05, Vol.45 (10), p.3855-3857
Hauptverfasser:	Zang, Shuangquan, Su, Yang, Li, Yizhi, Ni, Zhaoping, Zhu, Huizhen, Meng, Qingjin
Format:	Artikel
Sprache:	eng
Schlagworte:	Cadmium - chemistry Carboxylic Acids - chemistry Crystallography, X-Ray Ligands Models, Molecular Molecular Conformation Organometallic Compounds - chemistry Pyridines - chemistry
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Beschreibung
Zusammenfassung:	A novel 3D metal−organic framework [Cd2(m-bptc)(4,4‘-bpy)0.5(H2O)4]·H2O (1; m-H4bptc = 1,1‘-biphenyl-2,3‘,3,4‘-tetracarboxylic acid, 4,4‘-bpy = 4,4‘-bipyridine) with interweaving of triple- and single-helical chains has been obtained based on hydro(solvo)thermal reactions.
ISSN:	0020-1669 1520-510X
DOI:	10.1021/ic060286u