Aqua­(thio­sulfato-κ2O,S)[2,4,6-tri-2-pyridyl-1,3,5-triazine-κ3N2,N1,N6]zinc(II) hemihydrate

Aqua­(thio­sulfato-κ2O,S)[2,4,6-tri-2-pyridyl-1,3,5-triazine-κ3N2,N1,N6]zinc(II) hemihydrate

The title compound, [Zn(S2O3)(C18H12N6)(H2O)]·0.5H2O, contains two almost identical independent monomeric moieties composed of an octa­hedral Zn centre coordinated by a tridentate 2,4,6‐tri‐­2‐pyridyl‐1,3,5‐triazine (tpt) ligand, one aqua ligand and an O,S‐chelating thio­sulfate anion. The structure...

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Veröffentlicht in:Acta crystallographica. Section C, Crystal structure communications Crystal structure communications, 2006-05, Vol.62 (5), p.m192-m194
Hauptverfasser: Baggio, Sergio, Díaz de Vivar, M. Enriqueta, Baggio, Ricardo
Format: Artikel
Sprache:eng
Schlagworte:
Condensed matter: structure, mechanical and thermal properties
Exact sciences and technology
Physics
Structure of solids and liquids
crystallography
Structure of specific crystalline solids
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Zusammenfassung:The title compound, [Zn(S2O3)(C18H12N6)(H2O)]·0.5H2O, contains two almost identical independent monomeric moieties composed of an octa­hedral Zn centre coordinated by a tridentate 2,4,6‐tri‐­2‐pyridyl‐1,3,5‐triazine (tpt) ligand, one aqua ligand and an O,S‐chelating thio­sulfate anion. The structure is stabilized by a solvent water mol­ecule. Multiple strong hydrogen bonds with additional weaker π–π inter­actions between tpt groups define a multiple column spatial organization.
ISSN:0108-2701
1600-5759
DOI:10.1107/S0108270106010560