A one-dimensional coordination polymer, BBDTA.InCl4: possible spin-Peierls transition with high critical temperature of 108 K

A one-dimensional coordination polymer, BBDTA.InCl4: possible spin-Peierls transition with high critical temperature of 108 K

We have studied the crystal structure and magnetic properties of the organic radical cation salt, BBDTA.InCl4. This material formed a one-dimensional coordination polymer. Magnetic measurements indicated the spin-Peierls transition-like behavior at 108 K, which was higher than those typically observ...

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Veröffentlicht in:Journal of the American Chemical Society 2006-05, Vol.128 (18), p.6016-6017
Hauptverfasser: Fujita, Wataru, Awaga, Kunio, Kondo, Ryusuke, Kagoshima, Seiichi
Format: Artikel
Sprache:eng
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Zusammenfassung:We have studied the crystal structure and magnetic properties of the organic radical cation salt, BBDTA.InCl4. This material formed a one-dimensional coordination polymer. Magnetic measurements indicated the spin-Peierls transition-like behavior at 108 K, which was higher than those typically observed for the other organic spin-Peierls materials. The structural aspects of the lattice distortion from X-ray diffraction measurements at 50 K have been discussed.
ISSN:0002-7863