A Basket Tetradecavanadate Cluster with Blue Luminescence

A Basket Tetradecavanadate Cluster with Blue Luminescence

A blue luminescent tetradecavanadate compound, [Et4N]5[V14O36Cl], has been synthesized. It possesses an unprecedented half-open basket framework. Through the {ABAB}-type stacking, the {V14O36} clusters form infinite one-dimensional channels with considerable accessible volume in the crystalline stat...

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Veröffentlicht in:Journal of the American Chemical Society 2005-06, Vol.127 (24), p.8588-8589
Hauptverfasser: Chen, Lian, Jiang, Feilong, Lin, Zhengzhong, Zhou, Youfu, Yue, Chengyang, Hong, Maochun
Format: Artikel
Sprache:eng
Schlagworte:
Atomic and molecular clusters
Atomic and molecular physics
Exact sciences and technology
Optical properties of clusters
Physics
Studies of special atoms, molecules and their ions
clusters
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Zusammenfassung:A blue luminescent tetradecavanadate compound, [Et4N]5[V14O36Cl], has been synthesized. It possesses an unprecedented half-open basket framework. Through the {ABAB}-type stacking, the {V14O36} clusters form infinite one-dimensional channels with considerable accessible volume in the crystalline state.
ISSN:0002-7863
1520-5126
DOI:10.1021/ja0422209