A facile and chemoselective conjugate reduction using polymethylhydrosiloxane (PMHS) and catalytic B(C6F5)3

A facile and chemoselective conjugate reduction using polymethylhydrosiloxane (PMHS) and catalytic B(C6F5)3

A highly chemoselective conjugate reduction of electron-deficient Michael acceptors, including alpha,beta-unsaturated ketones, carboxylic esters, nitriles and nitro compounds with PMHS in the presence of catalytic B(C6F5)3 is described.

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Veröffentlicht in:Organic & biomolecular chemistry 2006-05, Vol.4 (9), p.1650-1652
Hauptverfasser: Chandrasekhar, Srivari, Chandrashekar, Gudise, Reddy, Marepally Srinivasa, Srihari, Pabbaraja
Format: Artikel
Sprache:eng
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Zusammenfassung:A highly chemoselective conjugate reduction of electron-deficient Michael acceptors, including alpha,beta-unsaturated ketones, carboxylic esters, nitriles and nitro compounds with PMHS in the presence of catalytic B(C6F5)3 is described.
ISSN:1477-0520
DOI:10.1039/b603610b