Catalysis in Capillaries by Pd Thin Films Using Microwave-Assisted Continuous-Flow Organic Synthesis (MACOS)

Catalysis in Capillaries by Pd Thin Films Using Microwave-Assisted Continuous-Flow Organic Synthesis (MACOS)

Finally …︁ metal in a microwave! Thin films of Pd black deposited onto the inner surface of microcapillaries are efficient for metal‐catalyzed transformations under flow conditions including the Suzuki–Miyama and Heck couplings. The reaction mixture is flowed through these miniature capillaries whil...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Angewandte Chemie International Edition 2006-04, Vol.45 (17), p.2761-2766
Hauptverfasser: Shore, Gjergji, Morin, Sylvie, Organ, Michael G.
Format: Artikel
Sprache:eng
Schlagworte:
cross-coupling
microwaves
palladium
synthetic methods
thin films
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:Finally …︁ metal in a microwave! Thin films of Pd black deposited onto the inner surface of microcapillaries are efficient for metal‐catalyzed transformations under flow conditions including the Suzuki–Miyama and Heck couplings. The reaction mixture is flowed through these miniature capillaries while being microwaved, and conversion times are on the order of seconds.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.200503600