An unusual dimerization of primary unsaturated alcohols catalyzed by RuHCl(CO)(PPh3)3

An unusual dimerization of primary unsaturated alcohols catalyzed by RuHCl(CO)(PPh3)3

When primary unsaturated alcohols were treated with a catalytic amount of RuHCl(CO)(PPh3)3 in benzene under reflux, dimerization reactions took place to give alpha-hydroxymethyl ketones as major product.

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Chemical communications (Cambridge, England) England), 2006 (17), p.1875-1877
Hauptverfasser: Doi, Takashi, Fukuyama, Takahide, Minamino, Satoshi, Husson, Guillaume, Ryu, Ilhyong
Format: Artikel
Sprache:eng
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:When primary unsaturated alcohols were treated with a catalytic amount of RuHCl(CO)(PPh3)3 in benzene under reflux, dimerization reactions took place to give alpha-hydroxymethyl ketones as major product.
ISSN:1359-7345
1364-548X
DOI:10.1039/b602103d