Rhodium-Catalyzed Tandem Vinylcyclopropanation of Strained Alkenes

Rhodium-Catalyzed Tandem Vinylcyclopropanation of Strained Alkenes

This communication reports an unusual rhodium-catalyzed 1,6-addition of a dienylboronate ester to highly strained alkenes. The resulting vinylcyclopropane-fused tricyclic products were produced in moderate to good yields. Preliminary mechanistic studies are also presented.

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Veröffentlicht in:Journal of the American Chemical Society 2006-04, Vol.128 (16), p.5338-5339
Hauptverfasser: Tseng, Nai-Wen, Mancuso, John, Lautens, Mark
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container_issue 16
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container_title Journal of the American Chemical Society
container_volume 128
creator Tseng, Nai-Wen
Mancuso, John
Lautens, Mark
description This communication reports an unusual rhodium-catalyzed 1,6-addition of a dienylboronate ester to highly strained alkenes. The resulting vinylcyclopropane-fused tricyclic products were produced in moderate to good yields. Preliminary mechanistic studies are also presented.
doi_str_mv 10.1021/ja060877j
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title Rhodium-Catalyzed Tandem Vinylcyclopropanation of Strained Alkenes
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