"On Water": Unique Reactivity of Organic Compounds in Aqueous Suspension

"On Water": Unique Reactivity of Organic Compounds in Aqueous Suspension

Water, the medium of choice: Many reactions, such as Claisen rearrangements (see scheme), are dramatically accelerated when performed in aqueous suspension (“on water”) relative to organic solvents or even neat conditions. Low miscibility of organic compounds with water is not detrimental: in fact,...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Angewandte Chemie International Edition 2005-05, Vol.44 (21), p.3275-3279
Hauptverfasser: Narayan, Sridhar, Muldoon, John, Finn, M. G., Fokin, Valery V., Kolb, Hartmuth C., Sharpless, K. Barry
Format: Artikel
Sprache:eng
Schlagworte:
Alkenes - chemistry
Azo Compounds - chemistry
Bridged-Ring Compounds - chemistry
click chemistry
cycloaddition
Epoxy Compounds - chemistry
interfaces
Ketones - chemistry
Molecular Structure
Naphthalenes - chemistry
Organic Chemicals - chemistry
Polycyclic Compounds - chemistry
rearrangement
Suspensions - chemistry
Water - chemistry
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:Water, the medium of choice: Many reactions, such as Claisen rearrangements (see scheme), are dramatically accelerated when performed in aqueous suspension (“on water”) relative to organic solvents or even neat conditions. Low miscibility of organic compounds with water is not detrimental: in fact, it facilitates the isolation of products.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.200462883