'Magic blue' - subtle reagent for EPR studies on H-abstraction from various substrates

'Magic blue' - subtle reagent for EPR studies on H-abstraction from various substrates

This paper is an EPR study on the generation of new ‘magic blue’ (MB) reagent containing bis{perfluoro[1‐(2‐fluorosulfonyl)ethoxy]ethyl}nitroxide 2 and perfluoro[1‐nitroso‐1‐(2‐fluorosulfonyl)ethoxy]ethane 3, both bearing chemically convertible terminal ω‐fluorosulfonyl group SO2F, and its H‐ion re...

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Veröffentlicht in:Magnetic resonance in chemistry 2006-05, Vol.44 (5), p.515-520
Hauptverfasser: Dou, Hong-Yan, Ni, Hong-Bo, Lin, Zheng-Huan, Zhao, Cheng-Xue
Format: Artikel
Sprache:eng
Schlagworte:
'magic blue' reagent
alcohol
aldehyde
arylalkane
H-abstraction
polymer
spin trapping
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Zusammenfassung:This paper is an EPR study on the generation of new ‘magic blue’ (MB) reagent containing bis{perfluoro[1‐(2‐fluorosulfonyl)ethoxy]ethyl}nitroxide 2 and perfluoro[1‐nitroso‐1‐(2‐fluorosulfonyl)ethoxy]ethane 3, both bearing chemically convertible terminal ω‐fluorosulfonyl group SO2F, and its H‐ion reactions from arylalkanes, alcohols, aldehydes and polymers, leading to a large number of new fluorinated nitroxides (FN). Copyright © 2006 John Wiley & Sons, Ltd.
ISSN:0749-1581
1097-458X
DOI:10.1002/mrc.1769