Temporary Phosphate Tethers: A Metathesis Strategy to Differentiated Polyol Subunits
Studies probing reactivity and selectivity of cross metathesis (CM) with an exocyclic olefin in a P-chiral bicyclo[4.3.1]phosphate triester are described. Studies have revealed a Type III CM reactivity pattern for the exocyclic olefin within this phosphate triester. This versatile method allows for...
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| Veröffentlicht in: | Organic letters 2006-04, Vol.8 (8), p.1673-1676 |
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| container_title | Organic letters |
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| creator | Waetzig, Joshua D Hanson, Paul R |
| description | Studies probing reactivity and selectivity of cross metathesis (CM) with an exocyclic olefin in a P-chiral bicyclo[4.3.1]phosphate triester are described. Studies have revealed a Type III CM reactivity pattern for the exocyclic olefin within this phosphate triester. This versatile method allows for simple, selective manipulation of a P-chiral building block en route to advanced polyol subunits. |
| doi_str_mv | 10.1021/ol0602809 |
| format | Article |
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| ispartof | Organic letters, 2006-04, Vol.8 (8), p.1673-1676 |
| issn | 1523-7060 1523-7052 |
| language | eng |
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| source | MEDLINE; American Chemical Society Journals |
| subjects | Alkenes - chemistry Molecular Structure Organophosphorus Compounds - chemistry Polymers - chemical synthesis Polymers - chemistry |
| title | Temporary Phosphate Tethers: A Metathesis Strategy to Differentiated Polyol Subunits |
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