One-Dimensional μ-Chloromanganese(II)−Tetrathiafulvalene (TTF) Coordination Compound

A new tetrathiafulvalene derivative 1 bearing a single pyridine group and its coordination complex 2, with stoichiometry [Mn(μ-Cl)Cl(1)2(CH3OH)] n , have been synthesized and fully characterized. The complex 2 shows an extended chain structure, which is potentially favorable for electrical conductiv...

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Veröffentlicht in:	Inorganic chemistry 2006-04, Vol.45 (8), p.3152-3154
Hauptverfasser:	Jia, Chunyang, Liu, Shi-Xia, Ambrus, Christina, Neels, Antonia, Labat, Gaël, Decurtins, Silvio
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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Beschreibung
Zusammenfassung:	A new tetrathiafulvalene derivative 1 bearing a single pyridine group and its coordination complex 2, with stoichiometry [Mn(μ-Cl)Cl(1)2(CH3OH)] n , have been synthesized and fully characterized. The complex 2 shows an extended chain structure, which is potentially favorable for electrical conductivity. Notably, this is the first monohalogen-bridged Mn(II) polymer exhibiting a moderate antiferromagnetic coupling between the Mn(II) centers.
ISSN:	0020-1669 1520-510X
DOI:	10.1021/ic060056f