A zinc(II)-based receptor for ATP binding and hydrolysis

A protonated Zn(II) complex with a terpyridine-containing pentaamine macrocycle catalyses ATP hydrolysis in the presence of a second metal ion, which acts as cofactor assisting the phosphoryl transfer from ATP to an amine group of the receptor.

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Bibliographische Detailangaben
Veröffentlicht in:	Chemical communications (Cambridge, England) England), 2005-05 (20), p.2630-2632
Hauptverfasser:	Bazzicalupi, Carla, Bencini, Andrea, Bianchi, Antonio, Danesi, Andrea, Giorgi, Claudia, Lodeiro, Carlos, Pina, Fernando, Santarelli, Samuele, Valtancoli, Barbara
Format:	Artikel
Sprache:	eng
Schlagworte:	Adenosine Triphosphate - chemistry Hydrogen-Ion Concentration Hydrolysis Molecular Structure Organometallic Compounds - chemistry Phosphates - chemistry Pyridines - chemistry Zinc - chemistry
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Beschreibung
Zusammenfassung:	A protonated Zn(II) complex with a terpyridine-containing pentaamine macrocycle catalyses ATP hydrolysis in the presence of a second metal ion, which acts as cofactor assisting the phosphoryl transfer from ATP to an amine group of the receptor.
ISSN:	1359-7345 1364-548X
DOI:	10.1039/b502229k