“Cation Pool” Method Based on C−C Bond Dissociation. Effective Generation of Monocations and Dications
The “cation pools” of alkoxyarylcarbenium ions were effectively generated by the oxidative C−C bond dissociation using low temperature electrolysis. The present method is especially effective for the generation and accumulation of dications, which react with carbon nucleophiles.
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| Veröffentlicht in: | Journal of the American Chemical Society 2005-05, Vol.127 (19), p.6930-6931 |
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| container_end_page | 6931 |
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| container_issue | 19 |
| container_start_page | 6930 |
| container_title | Journal of the American Chemical Society |
| container_volume | 127 |
| creator | Okajima, Masayuki Suga, Seiji Itami, Kenichiro Yoshida, Jun-ichi |
| description | The “cation pools” of alkoxyarylcarbenium ions were effectively generated by the oxidative C−C bond dissociation using low temperature electrolysis. The present method is especially effective for the generation and accumulation of dications, which react with carbon nucleophiles. |
| doi_str_mv | 10.1021/ja050414y |
| format | Article |
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| identifier | ISSN: 0002-7863 |
| ispartof | Journal of the American Chemical Society, 2005-05, Vol.127 (19), p.6930-6931 |
| issn | 0002-7863 1520-5126 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_67821470 |
| source | ACS Publications |
| subjects | Chemistry Electrochemistry Exact sciences and technology General and physical chemistry Kinetics and mechanism of reactions |
| title | “Cation Pool” Method Based on C−C Bond Dissociation. Effective Generation of Monocations and Dications |
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