“Cation Pool” Method Based on C−C Bond Dissociation. Effective Generation of Monocations and Dications

“Cation Pool” Method Based on C−C Bond Dissociation. Effective Generation of Monocations and Dications

The “cation pools” of alkoxyarylcarbenium ions were effectively generated by the oxidative C−C bond dissociation using low temperature electrolysis. The present method is especially effective for the generation and accumulation of dications, which react with carbon nucleophiles.

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Veröffentlicht in:Journal of the American Chemical Society 2005-05, Vol.127 (19), p.6930-6931
Hauptverfasser: Okajima, Masayuki, Suga, Seiji, Itami, Kenichiro, Yoshida, Jun-ichi
Format: Artikel
Sprache:eng
Schlagworte:
Chemistry
Electrochemistry
Exact sciences and technology
General and physical chemistry
Kinetics and mechanism of reactions
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Zusammenfassung:The “cation pools” of alkoxyarylcarbenium ions were effectively generated by the oxidative C−C bond dissociation using low temperature electrolysis. The present method is especially effective for the generation and accumulation of dications, which react with carbon nucleophiles.
ISSN:0002-7863
1520-5126
DOI:10.1021/ja050414y