Spherical Cluster Comprising a Four- and Six-Membered-Ring Motif

Spherical Cluster Comprising a Four- and Six-Membered-Ring Motif

Magic ball: A spherical aggregate containing a core of 32 inorganic atoms (see structure) was prepared by coordination of a cyclo‐P4 tantalum complex to copper(I) chloride. The phosphorus/copper core exhibits an arrangement of alternating four‐ and six‐membered rings, which are reminiscent of the hy...

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Veröffentlicht in:Angewandte Chemie International Edition 2006-04, Vol.45 (15), p.2473-2475
Hauptverfasser: Johnson, Brian P., Dielmann, Fabian, Balázs, Gábor, Sierka, Marek, Scheer, Manfred
Format: Artikel
Sprache:eng
Schlagworte:
cluster compounds
density functional calculations
fullerenes
phosphorus
tantalum
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Zusammenfassung:Magic ball: A spherical aggregate containing a core of 32 inorganic atoms (see structure) was prepared by coordination of a cyclo‐P4 tantalum complex to copper(I) chloride. The phosphorus/copper core exhibits an arrangement of alternating four‐ and six‐membered rings, which are reminiscent of the hypothetical Oh‐symmetric fullerene C32.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.200503511