Bipyridinium Ionic Liquid-Promoted Cross-Coupling Reactions between Perfluoroalkyl or Pentafluorophenyl Halides and Aryl Iodides

A new room-temperature ionic liquid has been synthesized from 2,2‘-bipyridine. This liquid improved the copper-catalyzed cross-coupling reactions between perfluoroalkyl or pentafluorophenyl halides and aryl iodides. Good recyclability using this solvent system was observed.

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Veröffentlicht in:Organic letters 2005-05, Vol.7 (10), p.1963-1965
Hauptverfasser: Xiao, Ji-Chang, Ye, Chengfeng, Shreeve, Jean'ne M
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container_end_page 1965
container_issue 10
container_start_page 1963
container_title Organic letters
container_volume 7
creator Xiao, Ji-Chang
Ye, Chengfeng
Shreeve, Jean'ne M
description A new room-temperature ionic liquid has been synthesized from 2,2‘-bipyridine. This liquid improved the copper-catalyzed cross-coupling reactions between perfluoroalkyl or pentafluorophenyl halides and aryl iodides. Good recyclability using this solvent system was observed.
doi_str_mv 10.1021/ol050426o
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title Bipyridinium Ionic Liquid-Promoted Cross-Coupling Reactions between Perfluoroalkyl or Pentafluorophenyl Halides and Aryl Iodides
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