Bipyridinium Ionic Liquid-Promoted Cross-Coupling Reactions between Perfluoroalkyl or Pentafluorophenyl Halides and Aryl Iodides

A new room-temperature ionic liquid has been synthesized from 2,2‘-bipyridine. This liquid improved the copper-catalyzed cross-coupling reactions between perfluoroalkyl or pentafluorophenyl halides and aryl iodides. Good recyclability using this solvent system was observed.

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Veröffentlicht in:Organic letters 2005-05, Vol.7 (10), p.1963-1965
Hauptverfasser: Xiao, Ji-Chang, Ye, Chengfeng, Shreeve, Jean'ne M
Format: Artikel
Sprache:eng
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Zusammenfassung:A new room-temperature ionic liquid has been synthesized from 2,2‘-bipyridine. This liquid improved the copper-catalyzed cross-coupling reactions between perfluoroalkyl or pentafluorophenyl halides and aryl iodides. Good recyclability using this solvent system was observed.
ISSN:1523-7060
1523-7052
DOI:10.1021/ol050426o