Construction of Asymmetric Fluorinated Carbon Centers

Construction of Asymmetric Fluorinated Carbon Centers

Various choices: Recent advances in the construction of asymmetric fluorinated carbon centers are discussed. Special attention is called to catalytic enantioselective reactions such as electrophilic fluorination (top) and decarboxylative allylation (bottom) of fluorinated substrates.

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Veröffentlicht in:Angewandte Chemie International Edition 2006-03, Vol.45 (14), p.2172-2174
Hauptverfasser: Prakash, G. K. Surya, Beier, Petr
Format: Artikel
Sprache:eng
Schlagworte:
asymmetric catalysis
asymmetric synthesis
Carbon - chemistry
enantioselectivity
Fluorine - chemistry
Hydrocarbons, Fluorinated - chemical synthesis
Hydrocarbons, Fluorinated - chemistry
Models, Molecular
Molecular Structure
organofluorine compounds
palladium
Stereoisomerism
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Zusammenfassung:Various choices: Recent advances in the construction of asymmetric fluorinated carbon centers are discussed. Special attention is called to catalytic enantioselective reactions such as electrophilic fluorination (top) and decarboxylative allylation (bottom) of fluorinated substrates.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.200503783