Metal-Rich, Neutral and Cationic Organotin Clusters

Tin can form examples of rare organically substituted clusters whose structures are related to Zintl salts. The two new types of metal‐rich organotin clusters, a neutral Sn9Ar3 (see picture) and two ionic [Sn10Ar′3]+ species, were structurally characterized and their bonding situation investigated b...

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Veröffentlicht in:	Angewandte Chemie International Edition 2005-04, Vol.44 (17), p.2546-2549
Hauptverfasser:	Richards, Anne F., Eichler, Barrett E., Brynda, Marcin, Olmstead, Marilyn M., Power, Philip P.
Format:	Artikel
Sprache:	eng
Schlagworte:	cluster compounds density functional calculations structure elucidation tin
Online-Zugang:	Volltext
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Beschreibung
Zusammenfassung:	Tin can form examples of rare organically substituted clusters whose structures are related to Zintl salts. The two new types of metal‐rich organotin clusters, a neutral Sn9Ar3 (see picture) and two ionic [Sn10Ar′3]+ species, were structurally characterized and their bonding situation investigated by density functional calculations.
ISSN:	1433-7851 1521-3773
DOI:	10.1002/anie.200500117