Synthetic Applications of α-Fluoroalkylated Enones. 1. Use as Dienophiles in Diels−Alder Cycloadditions

Synthetic Applications of α-Fluoroalkylated Enones. 1. Use as Dienophiles in Diels−Alder Cycloadditions

β-Fluoroalkylated enones are efficient dienophiles in Diels−Alder cycloadditions to prepare various fluorinated cylic compounds. However, the presence of the fluoroalkyl moiety modifies the reactivity and the selectivity of these cycloadditions.

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Veröffentlicht in:Journal of organic chemistry 2006-03, Vol.71 (7), p.2735-2739
Hauptverfasser: Leuger, Julia, Blond, Gaëlle, Fröhlich, Roland, Billard, Thierry, Haufe, Günter, Langlois, Bernard R
Format: Artikel
Sprache:eng
Schlagworte:
Chemistry
Exact sciences and technology
Organic chemistry
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Zusammenfassung:β-Fluoroalkylated enones are efficient dienophiles in Diels−Alder cycloadditions to prepare various fluorinated cylic compounds. However, the presence of the fluoroalkyl moiety modifies the reactivity and the selectivity of these cycloadditions.
ISSN:0022-3263
1520-6904
DOI:10.1021/jo052567+