Intramolecular Arene Hydroxylation versus Intermolecular Olefin Epoxidation by (μ-η2:η2-Peroxo)dicopper(II) Complex Supported by Dinucleating Ligand

Intramolecular Arene Hydroxylation versus Intermolecular Olefin Epoxidation by (μ-η2:η2-Peroxo)dicopper(II) Complex Supported by Dinucleating Ligand

A discrete (μ-η2:η2-peroxo)Cu(II)2 complex, [Cu2(O2)(H-L)]2+, is capable of performing not only intramolecular hydroxylation of a m-xylyl linker of a dinucleating ligand but also intermolecular epoxidation of styrene via electrophilic reaction to the CC bond and hydroxylation of THF by H-atom abstr...

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Veröffentlicht in:Journal of the American Chemical Society 2006-03, Vol.128 (12), p.3874-3875
Hauptverfasser: Matsumoto, Takahiro, Furutachi, Hideki, Kobino, Masashi, Tomii, Masato, Nagatomo, Shigenori, Tosha, Takehiko, Osako, Takao, Fujinami, Shuhei, Itoh, Shinobu, Kitagawa, Teizo, Suzuki, Masatatsu
Format: Artikel
Sprache:eng
Schlagworte:
Benzene Derivatives - chemistry
Copper - chemistry
Epoxy Compounds - chemistry
Hydroxylation
Kinetics
Ligands
Models, Molecular
Organometallic Compounds - chemistry
Pyridines - chemistry
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Zusammenfassung:A discrete (μ-η2:η2-peroxo)Cu(II)2 complex, [Cu2(O2)(H-L)]2+, is capable of performing not only intramolecular hydroxylation of a m-xylyl linker of a dinucleating ligand but also intermolecular epoxidation of styrene via electrophilic reaction to the CC bond and hydroxylation of THF by H-atom abstraction.
ISSN:0002-7863
1520-5126
DOI:10.1021/ja058117g