Cationic phosphorus-carbon-pnictogen cages isolobal to [C5R5]

The cationic cages nido-[C2Bu(t)2P2E]+ (E = As, Sb), which are isolobal to the cyclopentadienyl cation, adopt square based pyramidal structures with the heavy pnictogen atom at the apex; NMR and computational methods have been used to probe the dynamic behaviour of the complexes.

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Bibliographische Detailangaben
Veröffentlicht in:	Chemical communications (Cambridge, England) England), 2006-01 (13), p.1375-1377
Hauptverfasser:	Fish, Cheryl, Green, Michael, Jeffery, John C, Kilby, Richard J, Lynam, Jason M, McGrady, John E, Pantazis, Dimitrios A, Russell, Christopher A, Willans, Charlotte E
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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Beschreibung
Zusammenfassung:	The cationic cages nido-[C2Bu(t)2P2E]+ (E = As, Sb), which are isolobal to the cyclopentadienyl cation, adopt square based pyramidal structures with the heavy pnictogen atom at the apex; NMR and computational methods have been used to probe the dynamic behaviour of the complexes.
ISSN:	1359-7345 1364-548X
DOI:	10.1039/b517710c