Chiral N-Salicylidene Vanadyl Carboxylate-Catalyzed Enantioselective Aerobic Oxidation of α-Hydroxy Esters and Amides

A series of chiral vanadyl carboxylates derived from N-salicylidene-L-α-amino acids and vanadyl sulfate has been developed. These configurationally well defined complexes were examined for the kinetic resolution of double- and mono-activated 2° alcohols. The best chiral templates involve the combina...

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Veröffentlicht in:	Proceedings of the National Academy of Sciences - PNAS 2006-03, Vol.103 (10), p.3522-3527
Hauptverfasser:	Weng, Shiue-Shien, Shen, Mei-Wen, Kao, Jun-Qi, Munot, Yogesh S., Chen, Chien-Tien
Format:	Artikel
Sprache:	eng
Schlagworte:	Adducts Alcohols Ambient temperature Amides Catalysts Chemistry Crystallography Esters Kinetics Methanol Oxidation Physical Sciences Tetrahedrons Vanadates
Online-Zugang:	Volltext
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