A structurally characterized Ni-Al methyl-bridged complex with catalytic ethylene oligomerization activity

A structurally characterized Ni-Al methyl-bridged complex with catalytic ethylene oligomerization activity

A bimetallic Ni-Al (2.5087(15) A) complex with an agostic alpha-C-H, [eta-C5H4CH=N(C6F5)]Fe[eta-C5H4PPh2]Ni(AlMe3), has been isolated and crystallographically established. The complex is active towards ethylene oligomerization/polymerization under moderate conditions.

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2006-01 (12), p.1319-1321
Hauptverfasser: Weng, Zhiqiang, Teo, Shihui, Koh, Lip Lin, Hor, T S Andy
Format: Artikel
Sprache:eng
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Zusammenfassung:A bimetallic Ni-Al (2.5087(15) A) complex with an agostic alpha-C-H, [eta-C5H4CH=N(C6F5)]Fe[eta-C5H4PPh2]Ni(AlMe3), has been isolated and crystallographically established. The complex is active towards ethylene oligomerization/polymerization under moderate conditions.
ISSN:1359-7345
1364-548X
DOI:10.1039/b517824j